... of treatment chemical, bacterial degradation of treatment chemical, excessive ingress of oxygen, and poor water quality. The work presented was initiated to investigate a nitrite / molybdate corrosion inhibitor due to ongoing integrity concerns in the closed loop system. There is not clear published guidance...

... of potential waterside problem, and reduce corrosion problems since circulating water is not continuously saturated with oxygen. The three most reliable corrosion inhibitors for closed cooling water systems are chromate, molybdate, and nitrite. As mandated by environmental regulations, the use of chromate...

...Abstract The effect of nitrite and molybdate anions on the corrosion of mild steel in aerated, near neutral 8.6x10^-3 M (500 ppm) NaCl solution has been explored with weight loss, electrochemical, and optical microscopy techniques. Each moiety acts as an anodic inhibitor under...

...) was identified as the polymer carrier. Particle induced X-ray emission (PIXE) spectroscopy of anti-corrosion polymer films revealed significant concentration of molybdenum (Mo) implying that corrosion inhibitor composition was molybdate based. The films were divided into three groups according to different rates...

... that should be evaluated as part of a closed system treatment program. cleaning closed system filtration glycol molybdate nitrite corrosion control microbiological control deposition/scale control These factors are fundamental to any treatment program, however, there are other factors which must...

...tracer tag mass balance verified feed molybdate phosphate phosphonate polymer In discussing monitoring and the trends that have taken place over the past two decades, the obvious question is “what are the objectives that need to be satisfied?” Cooling water technology supplied by the major...

... or liquid streams from environments that do not support in situ growth of the organism ¹⁴ . Inhibition of SRB metabolism by nitrite and molybdate Because the formation of nitrite from nitrate is one possible mechanism by which NR-SOB inhibit SRB, the effect of nitrite on sulfide...

... technologies and highlights their advantages and disadvantages. azole closed system glycol molybdate nitrite phosphate phosphonate INTRODUCTION The dramatic rise in the number of electronic devices in the office place and the heat they put into the environment, coupled with demands for a comfortable...

... lead to corrosion of heat exchange surfaces. While a number of different approaches have been tried in the past, they all suffered from a variety of shortcomings. The use of molybdate to stop oxygen corrosion in low pressure steam boilers has been proven to be both effective and extremely operator...

... and molybdate concentration on the rates of general corrosion. The model has been incorporated into a program that makes it possible to analyze the effects of various conditions such as temperature, pressure, solution composition or flow velocity on corrosion rates. modeling prediction thermodynamics...

... if the pH is kept below 9.0. Proper pH control for this metallurgy is critical given its amphoteric nature, with corrosion accelerating significantly above pH 9.0. Molybdate, Nitrite, Azole, and Polymer - an effective program for mixed metal systems containing carbon steel, copper...

...Abstract Cyclic potentiodynamic polarization scans were conducted to determined the effectiveness of various combinations of anodic inhibitors in the prevention of pitting in carbon steel exposed to dilute radioactive waste. Chromate, molybdate, and phosphate were investigated as replacements...

... being placed on what is expected from a cooling water treatment, traditional inhibitors such as zinc and molybdate may not be acceptable. Another case that impacts cooling systems is where the make-up water quality is unchanged but demands for it may require the cooling system to operate at higher...

...-based fluids from a corrosion standpoint. Localized corrosion and build-up of corrosion products was a significant problem. The need for a corrosion test method designed for closed HVAC system fluid comparison is identified. brine corrosion inhibition nitrite molybdate heat transfer fluid glycol...

... and molybdenum additions independently and in certain combinations stimulate selective dissolution of iron, resulting in a significant enrichment of chromium beneath the passive film. In most cases, the formation of ferrous molybdate in the outer layers of the protective passive layer formed on stainless steels...

... a major western refinery will be presented as a case history. pitting inhibitor molybdate surface analysis amine oxide phosphonate INTRODUCTION Starting in the 1970’s, and accelerating over the intervening years, there have been several major trends that have developed which have influenced the types...

... the above operating parameters. brine calcium chloride corrosion inhibition chromate phosphate molybdate zinc Introduction In refrigeration terminology, a brine is any liquid-cooled refrigerant which is circulated as a heat-transfer fluid. Operating temperature of the cold-side of these brines range...

...Cathodic inhibitors such as zinc act to limit the cathodic reduction of oxygen and thus minimize the driving force to initiate pitting. Anodic inhibitors such as molybdate react to cut off the dissolution of iron from pits by precipitating in the pit interior under the low pH condition through...

... environmental concerns, alternative chemicals have been evaluated. By using surface analysis techniques it was possible to investigate the behaviour of a novel phosphonate and compare it to a known pitting inhibitor, molybdate. A mechanism is proposed that accounts for laboratory and field results...

...Abstract Surface characterization of inhibitor films has been attempted on a variety of metal samples from both laboratory and operating plants. These were evaluated to determine regions of molybdate and zinc accumulation relative to anodic and cathodic areas. The presence of molybdate in pits...