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Keywords: amines
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Proceedings Papers

...Recent Ionic Model Improvements A key weakness in the original commercially available ionic model was that it could not account for more than one amine reaction with HCl at a time. In the mid-2000s Mixed Solvent Electrolyte (MSE) model was developed by a joint industry project (JIP...
Proceedings Papers

... The model is suitable for simulating the phase behavior in refinery overheads because it is capable of simultaneously reproducing: Vapor-liquid and liquid-liquid equilibria between vapor, aqueous, and hydrocarbon-rich liquid phases Partitioning of various basic (e.g., amines and ammonia) and acidic (e.g...
Proceedings Papers

... * currently at Mustang Engineering, L.P Abstract New technologies for on-line monitoring and corrosion prediction to improve amine operation and reliability in Amine units is presented and discussed. A software package developed for corrosion prediction, allows to simulate the corrosive...
Proceedings Papers

...The reaction of an amine with hydrogen chloride (HCl) in crude unit vapor streams is a well-researched phenomenon. 1 The salts formed by these reactions can produce highly aggressive localized corrosion as well as fouling in crude unit columns, pumparound circuits and overhead...
Proceedings Papers

... components. Several components with regular intervals between boiling points were selected to map distillation data. A variety of types such as paraffins, napthenes and aromatics were included to achieve proper stream density. Desalter Phase Partitioning Model Abstract The use of organic amines...
Proceedings Papers

... and CO2 rich amine solution flows from the bottom of the absorber to the flash drum. Rich amine then flows from the flash drum through the lean/rich amine heat exchanger and on to the amine regenerator column. In the regenerator column, the acid gases are stripped from the solution by means of heat...
Proceedings Papers

... and environmentally acceptable manner. Safety issues include control of water level and overpressure. Environmental issues include restrictions on sewering boiler blowdown. Indoor air quality issues include the use of amines in steam used for humidification, sterilization and food preparation. Control of feedwater...
Proceedings Papers

...Neutralizing amines are typically added to the system in direct proportion to the amount of CO2 in the steam and are usually dosed at the concentration required to obtain condensate in the desired pH range. Neutralizing amine programs are most effective when fed to maintain a condensate...
Proceedings Papers

... Composition Reference Heating Systems: aqueous  - Tannin 15-25, Na-bipolyphosphonate 15-37, mix of Na and amine salts of naphthalene sulfonic acid 7-15, tungstates and molybdates 24-46, lanolin acids 11-25, polyethoxylated tail-oil fatty acids 30-40 wt. parts, in concn. 1.3-1.6 g/L of water; 85...
Proceedings Papers

... 1 Troubleshooting amine system corrosion problems Know the design concept and parameters  Is an up-to-date P&ID available?  age & circumstances behind need for system  what has changed since then?   Has the capacity been upgraded? how?  has the solvent been changed...
Proceedings Papers

...Abstract The causes and the prevention of carbon steel corrosion in refinery amine systems are reviewed. The corrosive agents are acid gases, ammonia, oxygen, heat stable salts, and amine degradation products. Corrosion mechanisms are provided for carbon steel exposed to amine solutions...
Proceedings Papers

... at 0 °C, 10 °C and 40 °C. It was found that hydrogen sulfide saturated anhydrous methanol exhibits similar corrosiveness for steel than hydrogen sulfide saturated water. Higher homologues showed decreasing corrosiveness. The diols and glycerols inhibit the hydrogen sulfide corrosion. Filming amines...
Proceedings Papers

... * Present Address: GE Nuclear Energy, Vallecitos Nuclear Center, P. O. Box 460, Pleasanton, CA 94566 Abstract Hydrothermal decomposition rate constants and high temperature pH values of some selected high-molecular weight amines and amino acids were measured under simulated steam generator...