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1-16 of 16
Keywords: SCWO
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Proceedings Papers
Supercritical Water Oxidation (SCWO) and the Army
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..., constantly adapting to new Army needs and research opportunities - ARO is not wed to any technologies and will drop a line of research and move on directly if we discover better alternatives. In my view, SCWO is now a viable alternative for destroying toxic military materials, but each situation must...
Proceedings Papers
Corrosion Control Methods in Supercritical Water Oxidation and Gasification Processes
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... been developed to allow successful continuous processing with sufficient corrosion resistance for an acceptable period of time. The present paper reviews the experience to date for methods of corrosion control in the two most prevalent SCW processing applications: supercritical water oxidation (SCWO...
Proceedings Papers
Corrosion-Potential Fluctuations and Polarization Resistance Measurements in High-Subcritical and Supercritical Water Oxidation Environment
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... subcritical water oxidation SCWO electrochemical noise analysis (ENA) electrochemical noise measurement (ENM) polarization resistance INTRODUCTION The use of high-subcritical and supercritical fluid is considered a key technology for an earth-friendly disposal process as well as for a next-generation...
Proceedings Papers
Corrosion in SCWO Plants Processing Chlorinated Substances: Aspects of the Corrosion Mechanisms and Kinetics for Binary Ni-Cr Alloys
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...supercritical water oxidation SCWO dichloromethane hydrogen chloride corrosion high temperature high pressure nickel chromium alloy 671 INTRODUCTION A major problem for the industrial application of supercritical water oxidation (SCWO) is to find a reactor material which can withstand...
Proceedings Papers
Electrochemical Noise Measurement on UNS 10276 in Oxidizing Hydrochloric Acid Solutions at High Temperature
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... at the temperatures below 210°C and above 330°C, and in these conditions, no corrosion traces were observed on the cross-sectional views. supercritical subcritical water oxidation SCWO noise analysis ENA nickel-base alloy corrosion monitoring INTRODUCTION Supercritical and high-subcritical water oxidation...
Proceedings Papers
Corrosion Investigations on Binary and Ternary Ni-Cr Alloys in SCWO Systems
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... by careful post-test examinations of corroded specimens (SEM, EDX, XRD, cross-sections). The results should serve as a basis for materials selection and development for SCWO ( S uper c ritical W ater O xidation) applications, especially for those in which acidic solutions are formed. supercritical water...
Proceedings Papers
Corrosion Resistant Materials for SCWO-Applications. Experimental Results from Long-Time Experiments
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... part of the tubes. In any case sulfuric acid and oxygen solutions are, for the reactors tested, much more corrosive than HCl or H3PO4 solutions. Abstract Corrosion during SCWO treatment is localized in the preheater and cooler sections of the apparatus. In former experiments...
Proceedings Papers
Corrosion of Nickel Based Alloy G-30 between 100 and 420°C, pH Values from 2 to 6 and Pressures Ranging from 250 to 480 Bar under Conditions of Supercritical Water Oxidation
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...Abstract Supercritical water oxidation (SCWO) is a promising and very effective method for the oxidation of organic wastes. Its high solubility for organic compounds and its special physical properties (i.e. density, viscosity) resulting in a key advantage over standard processes like incineration...
Proceedings Papers
Corrosion Behavior of Metals for SCWO Reactors for Organic Waste Processing Plants
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...Abstract Corrosion tests were conducted to select the material for the decomposition reactor using the SCWO process for organic wastes generated from nuclear plant. Examination conditions were determined assuming the decomposition of chloro-prene and cation exchange resin which generate chloric...
Proceedings Papers
Corrosion of Alloy 625 and Pure Chromium in Cl− Containing Fluids During Supercritical Water Oxidation (SCWO)
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... and analysed. The studies on chromium were performed exposing coupons (8x11mm) of ultra high purity to SCWO corrosion under equal conditions in a second autoclave (Alloy 625) of the same design. The coupons were taken out of the autoclave each 20 h and studied by X-ray diffraction. After 100 h, 200 h and 300 h...
Proceedings Papers
Comparison of Corrosion of Nickel and Chromium Based Alloys under Conditions of Supercritical Water Oxidation
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...Abstract Supercritical water oxidation (SCWO) is a promising and very effective method for the oxidation of organic wastes. Its high solubility for organic compounds and its special physical properties (i.e. density, viscosity) result in a key advantage over standard processes like incineration...
Proceedings Papers
The Initiation of Material Corrosion in Semicritical and Supercritical Aqueous Hydrochloric Acid Solutions
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...alloy 625 nickel molybdenum chromium alumina sapphire high-temperature water HCl Supercritical Water Oxidation SCWO INTRODUCTION In the supercritical water oxidation process (SCWO), hazardous or toxic organic contaminants in aqueous wastes are rapidly and quantitatively oxidized...
Proceedings Papers
Titanium as Reactor Material for SCWO Applications. First Experimental Results
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... loss from the large manufacturers tolerances. Also the concentration of titanium in the effluent is in almost all cases lower than 2 ppm. Abstract According to literature data, Nickel base alloys are not sufficiently corrosion resistant in chloride bearing SCWO environments. Titanium was proposed...
Proceedings Papers
Corrosion of High Temperature Alloys in Supercritical Water Oxidation Systems
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...Abstract Supercritical water oxidation (SCWO) is a promising and very effective method for the oxidation of organic wastes. Its high solubility for organic compounds and its special physical properties (i.e. density, viscosity) resulting in a key advantage over standard processes like incineration...
Proceedings Papers
Corrosion Phenomena of Alloy 625 in Aqueous Solutions Containing Sulfuric Acid and Oxygen under Subcritical and Supercritical Conditions
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... supercritical water SCWO INTRODUCTION The process of Supercritical Water Oxidation (SCWO) allows a conversion of organics to carbon dioxide and water 1 , 2 . The low values of density, dielectric constant and ion product let water act as a non-polar solvent in its supercritical state (T > 374 °C...
Proceedings Papers
Corrosion Phenomena on Alloy 625 in Aqueous Solutions Containing Hydrochloric Acid and Oxygen under Subcritical and Supercritical Conditions
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... the supercritical values of water. Abstract Alloy 625 is frequently used as reactor material for Supercritical Water Oxidation (SCWO) applications. This is due to the favorable combination of mechanical properties, corrosion resistance, price and availability. Nevertheless, the corrosion of alloy 625 like...