Crack initiation testing was performed on Alloy 800 (Fe-33Ni-21Cr) blunt-notched tensile specimens exposed to 0.55 mol/kg sulfate solutions at 280 °C with pH280C 3. These conditions were anticipated to produce a variety of sulfur-assisted degradation phenomena in Alloy 800 for the purpose of analytical TEM characterization. Initial imaging of the notch of Alloy 800 tensile specimens revealed a combination of environmentally-assisted cracking (EAC), intergranular corrosion (IGC), and pitting corrosion occurring up to approximately 50 μm in depth. Energy dispersive x-ray spectroscopy (EDX) of EAC revealed a mixture of Ti and Cr-rich oxides, with a sulfur layer at the oxide-metal interface, either incorporated in the oxide or as a sulfide compound associated with Ti. EDX characterization of pitting corrosion indicated only minor oxide formation at the pit-metal interface, with clear identification of a nano-scale sulfur layer at the pit-metal interface, accompanied by a relatively low concentration of oxygen and major alloying elements. The sulfur layer could indicate adsorption of sulfur on the bare metal with near complete surface coverage during pitting, which effectively limits lateral oxide growth and accelerates metal dissolution in the underlying region. Further details on the mechanistic interpretation of results will be discussed.

Subject
Pits, Environmental cracking, Sulfur, Nickel based alloys, Sulfates, Transmission electron microscopy, Crack initiation, Corrosion cracking, Material degradation, Interfaces, Characterization tests, Pitting, Alloys
Keywords:
environmentally assisted cracking, pitting, Tem, acid sulfate, Alloy 800
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2019
Association for Materials Protection and Performance (AMPP)
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