The use of phosphorus based inhibitors is a common strategy to control naphthenic acid corrosion. Some users have experienced phosphate fouling that has been attributed to use of these inhibitors. As a result, some have limited the amount of allowable phosphorus, potentially reducing flexibility to safely use high TAN (Total Acid Number) opportunity crudes.

Improved understanding of the corrosion inhibitor chemistry helps to explain the mechanisms of fouling. This improved understanding has led to design of new inhibitors that control corrosion with reduced fouling. The improvement in chemistry in combination with improved monitoring technologies is changing perspectives on TAN Management in Refining.

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