This paper deals with study on hydrogen diffusion and permeation in two pipeline steel materials. Some criticisms on the electrochemical hydrogen permeation technique were discussed in this article deals mainly with trapping effect on diffusion of hydrogen with steel. The effects of some metallurgical features such as microstructure were evaluated studying hydrogen diffusion on the same materials in as received condition, fully quenched and annealed conditions. Results were compared with steel pipeline not specifically produced for sour service. Lattice diffusion coefficient of hydrogen was estimated with simple increase and decrease of cathodic charging current (partial transient).

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