Rust preventatives based on sodium, calcium, zinc, or barium sulfonates are commonly employed by manufacturers of metal products to protect their products from a variety of corrosion pathways. Although the films are nearly imperceptible, the protection they provide can last several months to a year or more depending on the environment. Historically, barium-sulfonate-based rust preventatives have been touted as superior products as compared to other alkali metal sulfonates. These barium-based products, however, can be a disadvantage to users and manufacturers due to the higher cost of barium waste disposal. Future environmental regulations are expected to tighten, but there has been a reluctance to switch from barium-based products by the manufacturing segment due to a perceived performance advantage. Accelerated testing methods have been employed to demonstrate that calcium-based rust preventatives can provide equal or better performance than barium-based products. Performance of the materials was measured against industry standard controls.

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