Stress assisted corrosion (SAC) of carbon steel boiler tubes is one of the major causes of waterside failure in industrial boilers. SAC is a major concern for kraft recovery boilers in the pulp and paper industry as any water leak into the furnace can cause a smelt-water explosion in the boiler. Failed carbon steel boiler tubes from different kraft recovery boilers were examined to understand the role of carbon steel microstructure on crack initiation and SAC crack morphology. A number of carbon steel tubes showed a deep decarburized layer on the inner surface (water-touched) and also an unusually large grain size at the inner tube surface. SAC cracks were found to initiate in these areas with large-grained-decarburized microstructure. Tubes without such microstructure were also found to have SAC cracks. It was found that the decarburization and large grained microstructure may facilitate initiation and growth but is not necessary for SAC of carbon steel boiler tubes.

Subject
Steel surfaces, Oxides, Microstructure, Tubes, Corrosion cracking, Stress cracking, Stress, Oxide surfaces, Internal surfaces, Surface layers, Boilers, Carbon steel, Cracks
Keywords:
Stress Assisted Corrosion, Carbon Steel, Boiler Tubes, Corrosion Fatigue
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2007
Association for Materials Protection and Performance (AMPP)
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