Polyamide-11 undergoes a chemical aging process, caused by hydrolysis that gradually reduces the polymer's ductility and molecular weight. This is well understood and well documented in the open literature. The effects of hydrolysis on the mechanical properties of plasticized polyamide-11 as a pipeline liner are less well understood. This paper describes a study in which liners are subjected to accelerated aging by hydrolysis followed by multiple buckling cycles. The effects of molecular weight gradient through the liner wall, residual plasticizer content, and the installed stress state of the liner will be described.

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