As new advanced surface analysis techniques are developed, previously inaccessible information relating to scaling processes can be studied. In this paper the introduction of the Atomic Force Microscope (AFM) as one of the family of scanning probe techniques is presented for the study of calcareous deposition under an applied potential. In the paper the potential for using in-situ AFM is presented and the limitations in its use are assessed. The AFM will facilitate viewing, at a micro or nanoscopic level, surfaces processes relating to nucleation and growth of scale and will offer new insights into scaling processes and mechanisms.

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