Abstract
The detrimental effects of chloride attack on the steel within reinforced concrete structures are well known, and a number of solutions are available for repair and rehabilitation where the process has resulted in significant deterioration of the structure. An effective method of extending the life of chloride contaminated structures is to electrochemically treat the steel using either a temporary (chloride extraction) or permanent (cathodic protection) process. Shifts in steel potential are accepted as a measure of effectiveness, but this work demonstrates a greater significance of other effects of electrochemical treatment. An analysis of the available data suggests that electrochemical treatments may modify the chemistry at the steel/concrete interface and this has beneficial effects on steel passivity. Electrochemical treatments are effective in increasing the chloride threshold level, and hence the time to initiation of chloride induced corrosion. This impacts on the remaining service life of a concrete structure.