Three failure analyses involving iron-nickel-chromium alloys (Alloy 800H and niobium modified HP-40) in high temperature steam service 1300°F to 1450°F (704°C to 788°C) are presented. Boiler water carryover conditions led to steam-side salt deposits containing sodium, chlorine, and sulfur species. The unique conditions of extremely high temperatures and localized accumulation of aggressive salt species resulted in component failures that involved a molten salt attack mechanism not typically observed in steam-side environments.

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