Commercial magnesium anodes were evaluated using ASTM G97-89 as standard test and attached to the ASTM test arrangement a technique of electrochemical impedance was also used. Cylindrical samples were cut from the as-cast Mg anodes. Several heat treatments and different cooling rates were carried out. The anodic efficiency was determined as a function of the cooling rate, showing an increment around 10 to 12% above the efficiency showed by the non-treated commercial anodes (as-cast condition). The efficiency increments were related to the microstructural characteristics i.e particle size and/or grain size. Also some morpholgical aspects were considered.The appearance of second phase particles influences the different forms that the corrosion process exhibits.

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