A reduction in the availability and in the quality of water, coupled with more significantly more stringent water discharge restrictions, has resulted in increasing numbers of industrial complexes investigating water reuse and zero liquid discharge. Their investigation generally includes a survey of the potential impact of increased dissolved solids on the formation of mineral salt scales on heat transfer surfaces. These predictive tools are readily available and fairly accurate. The prediction of corrosion potential, however, is not as clearly defined, and as a consequence, little consideration is given to the effects of increased solids on corrosion. In addition to the potential for accelerated corrosion related to increased dissolved solids, many reuse waters contain elevated levels of biological activity and are rich in the nutrients that feed these micro organisms. This paper looks at the reasons for selecting zero liquid discharge as a means of water conservation and discharge reduction, the unit operations available to achieve these goals, and the corrosion mechanisms and mitigation associated with reuse water.

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