A method of treatment by reverse osmosis (RO) has been developed and implemented for the treatment of waste waters from organic acid cleaning applied to the chemical cleaning of power plant once-through boilers. Concentrate waste waters containing COD and nitrogen components, such as ammonia and dilute waste waters from water washing, are separately stored. The concentrate waste water is treated by RO into a dilute permeate and a thickened waste water. By repetition of this process, the waste water volume is reduced to 1/4-1/6 of the original. In the permeate, COD and ammonia concentrations are as low as below 1/100 of those before treatment. The resulting dilute permeate and the dilute waste water from water washing are mixed together and subjected to chemical oxidation and decomposition treatment to further reduce COD to below 10 mg/l. The results of treatment are also shown.

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