Polyphosphates are effective inhibitors to control a variety of problems in potable water distribution systems. They are produced from the condensation reaction between phosphoric acid and a base. The Na2O:P2O5 ratio determines the chain length. Polyphosphates are cathodic inhibitors and provide good carbon steel corrosion control. The addition of zinc is synergistic, further reducing corrosion and accelerating protective film formation. Polyphosphates are excellent threshold calcium carbonate inhibitors. They also are capable of stabilizing dissolved iron and manganese and preventing "red" and "black" waters. During pigging operations, zinc polyphosphate provides steel protection by preventing flash rusting and disperses corrosion by-products.

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