Modern electrochemical corrosion monitoring methods have been employed successfully for several years to investigate aqueous corrosion in power plant environments. In a recent study conducted by Westinghouse, similar equipment was used to evaluate high temperature corrosion behavior. Electrochemical probes were located in the radiant section and superheater inlet of a steam generator unit to investigate corrosion activity caused by changes in the combustion environment. The results obtained are encouraging and typical data are presented to illustrate steady state and unstable corrosion behavior during normal plant operations. The indications are that modern instrumentation can offer a considerable opportunity to optimize materials selection and improve reliability, safety and resource utilization.

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