Very low concentrations of thiosulfate ions can dramatically enhance pitting corrosion of austenitic stainless steels in natural waters or dilute process streams. Pitting can occur, even in chloride-free environments, provided another anion like sulfate is available to support acidification of the pit. Thiosulfate can also enhance, but only to a limited extent, the propagation of crevice corrosion. In this review, the mechanistic aspects and practical consequences of thiosulfate corrosion are summarized.

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