Abstract
The selection of materials of construction is a major factor in the success of many processes in an oil refinery. Three areas which have substantial impact in selection of materials are corrosion resistance, mechanical properties and economics. Several materials are considered for reactor vessels, heaters, feed-effluent exchangers and hot transfer lines of the hydrotreating processes. Although hydrotreating and hydrodesulfurization processes vary, they all involve using hydrogen to remove sulfur and other impurities from petroleum products at elevated temperatures. There are several corrosion mechanisms which are possible in these processes. Three of these mechanisms are high temperature sulfide corrosion, polythionic acid (PTA) stress corrosion cracking (SCC) and chloride SCC.