Low carbon steel (LCS) exposed to concentrated solutions of urea-ammonium nitrate (UAN) can develop either a fully or a partially passive film. The integrity of the film phase that develops depends primarily on pH and, to a lesser extent, on nitrate ion concentration. Urea interacts synergistically with nitrate in the presence of low-carbon steel; surface adsorption may be the mechanism leading to higher true current densities. Based on this information, an inhibitor was developed that protects the naturally formed passive film from pH depressions.

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