This paper provides a review of how basic inhibition of industrial boiler waterside deposition has evolved from phosphate conditioning to current chelant and polymer technologies. The benefits, and limitations of polymers are reviewed. On-line results monitoring is discussed as a proven approach to determining the relative efficacy of internal treatment programs. Lastly, new boiler water test procedures for EDTA and carboxylated polymers are highlighted as important elements of a cost-effective deposit control program.

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