Abstract
Lack of knowledge of the formation of corrosion films, their chemical nature, and protecting properties prevents reliable predictions of the CO2 corrosivity of gas - condensate - and oil wells. In long transport pipes the water phase accumulates increasing amounts of Fe2+ corrosion product during the travel. As the Fe2+ concentration has a major influence on CO2 corrosion, exposure facilities enabling controlled variations of the Fe2+ concentration have been used. The influence of en-vironmental variables on film formation have been studied. Three different types of corrosion films were detected. The nature of the films, their ability to slow down the corrosion rate, their electrochemical breakdown and the localized attack resulting from the film breakdown have been investigated.