This paper briefly reviews the history of fluoroelastomeric coatings as linings for flue gas desulfurization scrubber units. It describes the basic characteristics of fluoroelastomers and illustrates their success in the original design applications of the first generation lining systems. The first generation fluoroelastomers had less successful applications in retrofit flue gas desulfurization units than similar applications in new facilities; it was subsequently shown that this was due to improved performance with a heat cure. Normal start-up conditions of new facilities provided this essential heat cure. Because of the more rapid exposure to operating conditions with retrofit FGD installations, second generation fluoroelastomers were needed to provide suitable performance. This paper illustrates the successful development of such materials.

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