Abstract
The selection of heat-resistant alloys is reported in terms of hot corrosion mechanisms that are common to their use in carburizing and sulfurizing environments. Data based on laboratory oxidation tests and carburization tests are presented. Coupon exposure of heat-resistant alloys having a wide variation in alloy content has been implemented in waste disposal units used in dissimilar applications. The mode of hot corrosion and the rates of corrosion have been determined.
Intergranular oxidation associated with carburization has been the mode of hot corrosion in an incinerator for pyrolyzing waste solvents, paints, and spent aircraft fuel. Sulfidation has been observed in a pyrolyzer used for converting rubber tires to carbon black. Carburization, sulfidation and severe chromium depletion have been observed in a third unit.