High levels of chlorine under upset conditions have been shown to be aggressive to copper and brass alloys protected with the common azoles used in current cooling water treatment programs. Little is known about bromine chemistry under similar conditions. Preventing the attack of copper and brass under upset conditions will reduce corrosion rates and, consequently, prolong equipment life.

This work shows that dimethylhydantoin is capable of reducing the corrosion rate caused by chlorine upsets on tolyltriazole inhibited brass. Bromine is also shown to be less aggressive than chlorine toward tolyltriazole treated surfaces.

You do not currently have access to this content.