Abstract
Mechanical properties up to 400°C and microstructural evolution of Duplex 22 and 25% Cr stainless steel tubing have been determined as a function of the amount of cold working. The following nominal mechanical grades (ksi) were considered: 75 for extruded and quenched (EQ) tubing; 110 and 125, obtained by cold drawing up to 10 and 20% of reduction of area (RA) respectively; 140, obtained by means of cold pilgering at RA of 50%.
Susceptibility to SSCC has been determined in an acidified (pH ≃ 2.7) sour environment in the temperature range 22-140°C through engineering diagrams based on the pass-fail criterion. Thus, the critical NaCl concentration and pH2S have been determined as a function of cold working for qualification and selection of duplex steel tubing most suitable for use in a given environment. Cold worked tubing maintains the corrosion performance of EQ tubing up to grade 125 for D25 and grade 110 for D22. A marked reduction in SSCC resistance has been observed for D22-125 and for both D22-140 and D25-140.