Abstract
Corrosion tests were carried out on C-steel (API 5L X70) and 13Cr steel (AISI 420) materials in a 3% NaCl solution containing sand particles (5000-9000 ppm) and saturated with CO2 at defined partial pressure (0-0.3 MPa) and temperature (30- 60°C). The effect of residual O2 content (10-1500 ppb) was further examined.
Two flow geometries were studied: 1) undisturbed pipe flow and 2) submerged jet impinging (30-90°) onto a flat plate. The effect of specimen surface treatment (shot-blasting or pickling) was examined with dry polished material as a reference. Weight-loss and electrochemical measurements were applied to determine average and instantaneous corrosion rates respectively.
The results are discussed in relation to fluid flow conditions and the surface preparation/microstructure of materials tested. No stable corrosion product layers retarding CO2 corrosion were formed within the testing time-frame. (<100 h). Consequently no erosion-corrosion associated with physical degradation of protective layers occurred. Enhanced corrosion of C-steel specimens has been related to the induced plastic deformation and disruption of the metal surface layer stimulating corrosion attack.