Abstract
The effect of galvanic coupling of some experimental ELI superferritic stainless steels with some less noble metallic materials was evaluated in synthetic sea water under constsnt strain rate conditions. Times to failure of the stainless steels are markedly shortened by coupling with Zn, Al + 4% Zn and Mg, being the corrosion potentials shifted down to the potentials where hydrogen evolution occurs. Coupling with more noble metallic materials like Admiralty brass does not effect the stress-strain behaviour and ductile fracture occurs. Coupling with Armco iron does not effect the stress-strain behaviour but SEM fractographs indicate the occurrence of hydrogen up-take. Evidence of hydrogen embrittlement at potentials ranging -0.7V s.c.e. was also found on uncoupled specimens under potentiostatic control. Maximum care must be taken for galvanic coupling and cathodic protection of these stainless steels,leading to corrosion potentials at -0.7V s.c.e. or below.