A study has been made of mill annealed and cold worked duplex Dalmine D22 and D25 stainless steels (75 and 140 ksi) and of cold worked superaustenitic steel Dalmine D28-32 (110 ksi).

The materials have been tested under conditions typical of oil and natural gas wells operating in a severe environment.

The effect of environment variables (T, pCO2, pH2S, NaCl concentration and pH) and of cold working on corrosion properties, particularly SSCC, has been investigated.

Engineering diagrams have been produced for qualification and selection of the material most suitable for use in a given environment.

In the case of the duplex steels, the corrosion mechanisms in relation to environmental variables, applied stress and microstructure have been examined from the microstructure aspect.

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