Laboratory weight loss corrosion tests were performed on two types of commercially available corrosion resistant alloys (CRA), 13Cr martensitic stainless steel and a duplex alloy (22% Cr, 5 1/2% Ni, 3% Mo ferritic-austenitic stainless steel), in simulated acidizing environments of 15% hydrochloric acid and 12%-3% hydrochloric-hydrofluoric acid mixture (12-3 HCl-HF). Inhibition of these alloys by proprietary low alloy inhibitors has provided only marginal results as well as a sensitivity to the presence of fluoride. Use of newly developed high alloy inhibitors has enabled corrosion control at elevated temperatures and partially removed the sensitivity to fluoride ion.

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