Several materials were evaluated for use in nuclear steam generators (NSG). These materials were exposed to corrosive conditions representative of those found in nuclear steam generators. The materials evaluated were gold, titanium, tantalum, niobium, Hastelloy C-276, Hastelloy G, Nickel 200, nickel- base Alloy 625, and heat-treated nickel- base Alloy 600. The test environments simulated acid pitting attack, caustic stress corrosion cracking and reduced sulfur attack.

In the pitting environment, the monolithic materials did well, however Nickel 200, nickel-base Alloy 600 and Hastelloy G3 did poorly. The remaining alloys, nickel-base Alloy 625 and Hastelloy C-276 were relatively unaffected in the pitting environment.

Tantalum, titanium, niobium, nickel-base Alloy 625 performed poorly in the environment designed to evaluate resistance to caustic cracking. Nickel- base Alloy 600 (stress-relieved), Hastelloy C-276, Hastelloy G-3 and Nickel 200 compared fair to good in the caustic sodium. The gold was unaffected in the hot caustic solution.

In the environment selected to represent a reduced sulfur environment, nickel-base Alloy 625 and Hastelloy C-276 exhibited considerable resistance. The nickel-base Alloy 600 was attacked within a relatively short period of time.

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