Cooling Tower #5 is a new tower started up in April, 1980. The tower system was built for non-chromate water treatment. The specific phosphate treatment method was chosen after extensive testing. Immediately upon startup corrosion problems that were not indicated in the testing were found. Carbon steel corrosion rates were greater than .175 mmpy and admiralty corrosion rates were above .013 mmpy. Reversion rates of polyphosphate to orthophosphate varied and high fouling rates occurred. Several changes in chemicals and other control parameters have been made. The carbon steel corrosion rates have decreased to less than .013 mmpy. The copper corrosion monitors indicate a corrosion problem but equipment inspections do not verify this problem.
This paper describes the changes to cooling water chemistry made in the first year of operation. Data from coupons, a NACE test heat exchanger and Petrolite PAIR probes are presented to show what each change did for admiralty and carbon steel corrosion inhibition. Visual inspection reports are detailed to provide information on fouling rates caused by these changes.