While many studies have been made on the corrosion and stress corrosion behavior of austenitic and ferritic stainless steels, relatively few investigations have been conducted into the corrosion and stress corrosion properties of duplex stainless steels. The brief body of literature on the corrosion of duplex stainless steels is primarily concerned with the corrosion properties of as-annealed, cast duplex stainless steel.1-3- Little attention has been given to the effect of heat treatments and microstructural changes on the corrosion characteristics. However, during the early investigations of austenitic stainless steels, several studies were conducted in the United States,4  England,5  and Germany6  which indicated the superior intergranular corrosion resistance of stainless steels containing 20-40 v/o (volume percent) ferrite. No theoretical explanation was provided for their good behavior. These studies, apparently, went largely unnoticed since little commercial use was made of duplex stainless steels, other than to take advantage of their high alloy content and employ them as weld metals.

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