Historically, as better high-temperature alloys are developed, furnace users increase the temperature or severity of the furnace operating conditions in their quest for more product or a more desirable ratio of products in the outlet stream. As a result, furnace parts are consistently operating at or near their maximum potential. This, coupled with stresses created during rapid shutdown and start-ups (both scheduled and unscheduled), makes furnace parts prone to fail. During the past several years, we have done several failure analyses of high-temperature materials from an ethylene plant, an ammonia plant and a coal gasification pilot plant and have followed many of these with laboratory or field tests aimed at understanding and preventing the recurring and more expensive failures.

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