Many of the failures in nickel and nickel base alloys can be related to special but as yet not understood compositional features of surfaces and grain boundaries. Compositional differences occur as a result of solute (and/or impurity) segregation or precipitation (1, 2, 3). For example, it is possible that impurities at the ppm level in the matrix can be enriched by factors of 103 ~ 104 at grain boundaries and surfaces during heat treatment or thermal processing.

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