Corrosion of metallic and refractory components in refinery furnaces and boilers, central power stations, ships boilers and other equipment where heavy residual fuel oils are fired, is primarily caused by contact with slags formed by the heavy metals present. Fuels refined from crude oils produced in Venezuela, other Caribbean sources and the Western United States and Canada have high concentrations of vanadium and other metals. These metals are present as organometallic compounds called porphyrins, which are concentrated during the refining process and also as entrained salts such as NaCl(1, 2).

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