In a non-isothermal flowing sodium/stainless steel system iron, chromium, and nickel are dissolved from the high-temperature regions and deposited in the lower temperature regions because of supersaturation. Included in this process of mass transfer is the formation and decomposition of various transition metal and sodium double oxides. In addition, the formation of a double-oxide would also lower the oxygen activity in the sodiun system if the double oxide is thermodynamically more stable than Na2O. The main objective of the present study is to assess the effect of double oxides, particularly sodium chromite (NaCrO2), on the oxygen activity in a typical sodium/stainless steel system.
Subject
Materials,
Oxide formation,
Chromium,
Vanadium,
Wiring,
Liquids,
Free energy,
Sodium,
Steel,
Oxygen,
Stainless steel,
Samples,
Sampling
© 1974 Association for Materials Protection and Performance (AMPP). All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means (electronic, mechanical, photocopying, recording, or otherwise) without the prior written permission of AMPP. Positions and opinions advanced in this work are those of the author(s) and not necessarily those of AMPP. Responsibility for the content of the work lies solely with the author(s).
1974
Association for Materials Protection and Performance (AMPP)
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