It is a specific feature of the corrosion phenomena in the petroleum industry that it occurs in a two-phase medium (water and hydrocarbon). It can easily be shown that the rigorous elimination of water reduces corrosion rates to an almost negligible level; it does not, however, follow that water soluble inhibitors are the most efficient. To the contrary, oil soluble inhibitors are found to be much more active. While the latter show activity in the low ppm range, the water soluble inhibitors are almost always used from 100 ppm on up, generally between 1,000 - 10,000 ppm. As a consequence, oil soluble corrosion inhibitors, such as used in the petroleum industry, must necessarily be evaluated in a two-phase system. This has a number of consequences which will be discussed in various contexts throughout this paper.

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