A deaeration process and an ammonia addition are made during shutdown periods for a thermal power plant operated using Oxygenated Water Treatment (OT). This paper describes the effects of such water condition changes on corrosion behaviors of carbon and low alloy steels, particularly from the viewpoint of oxide film characteristics. As hematite films formed by OT tend to dissolve under the All Volatile Treatment (AVT) condition, the corrosion proceeds in a stepwise manner due to the condition changes. Preoxidation in high pH and high dissolved oxygen concentration water (HipH/DO) forms very protective oxide films on the steels and suppresses corrosion in the OT condition.

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