Stress corrosion cracking (SCC) behaviors of four austenitic Fe-32Mn-9Al containing approximately 1 wt% carbon alloys were studied in this work. All of the four alloys are susceptible to stress, corrosion cracking in room temperature and 160°C NaCl solution. The SCC can be enhanced by applying anodic potential. The mechanism of SCC is mainly active path corrosion. The crack path is transgranular. The addition of 1.23% Mo or 1.27% Si to the austenitic Fe-32Mn- 9A1 alloy does not change the SCC mechanism and crack path. The addition of 1.27% Si makes the alloy more susceptible to SCC but no such effect was observed with 1.23% Mo. All four alloys studied are susceptible to hydrogen embrittlement in 3.5% NaCl solution at negative enough cathodic applied potential. The addition of Mo, Cr or Si in the alloy displaces the embrittlement potential to a more cathodic range.

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