A low carbon steel was heat-treated by various processes, so that different microstructures including ferrite + pearlite, bainite, bainite + martensite, martensite, and temper martensite were obtained. These heat-treated specimens were used to evaluate the hydrogen embrittlement characteristics by HIC immersion test and Charpy impact test. The results indicated that hydrogen cracking in the as-received specimen is the worst and the air cooling, oil cooling and high temperature tempered specimens have the better HIC resistance. These results demonstrated that the pearlite band structure is the most important HIC propagation path. The Charpy impact testing results for specimens without and with hydrogen charging showed that the absorbed energies of H-charged specimens did not change or even increase. The dislocation density seems to play an important role on the variation of impact absorbed energy. The detail effects of microstructure on the hydrogen embrittlement was discussed in this paper.

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