Conceptual designs of advanced combustion systems that utilize coal as a feedstock require high temperature furnaces and heat transfer surfaces capable of operation at much elevated temperatures than those prevalent in current coal-fired power plants. The combination of elevated temperatures and hostile combustion environments necessitate developement/application of advanced ceramic materials in these designs. The present paper chracterizes the chemistry of coal-fired combustion environments over a wide temperature range of interest in these systems and discusses preliminary experimental results on several materials with potential for application in these systems.

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