This paper will review the brief history in the literature of the inhibition of corrosion resistant alloys (CRA's) in acidic stimulation fluids. This review primarily discusses the problems associated with inhibiting 13% Cr and 22% Cr duplex steels in hydrochloric (HCl) and hydrochloric-hydrofluoric (HCl-HF) acid systems using low alloy inhibitors and the successes achieved using high alloy inhibitors. Other areas briefly discussed are the repassivation of 13% Cr and 22% Cr, effect on nickel-based alloys and use of organic acids.

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