All too often mineral scale formation is viewed purely in terms of supersaturation. More recently, studies of barium sulfate scale inhibition in acidic reservoir brines have identified pH as a factor which does not significantly affect supersaturation but, nonetheless, incapacitates many scale inhibitors. This paper explores significant perturbation of an oilfield barium sulfate inhibited scale system by various divalent cations and anions. The chemistry which affects inhibitor-crystal interaction is presented as the principle influence upon inhibitor function.

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