Protective coatings for both titanium-aluminum (Ti-Al) alloys and for carbon-carbon (CC) composites have been synthesized and characterized for hypersonic vehicle applications. Coatings of choice must show protection against oxygen and hydrogen both under mild environments of low flows and low temperatures and under severe environments of high flows and high temperatures. Aluminum-silicate glass ceramics were chosen as coating candidates because they are materials that are stable to temperatures of 1500°C, are nonreactive to oxygen, and have minimal reactivity with respect to hot hydrogen. This paper will discuss the chemistry of the coating synthesis and application as well as the characterization of such coatings.

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