Abstract
This paper summarizes the results of a research study in which the localized corrosion of two corrosion-resistant alloys (CRAs) were evaluated. The two alloys investigated (Alloy UNS N08825 and Alloy UNS N06975) were found to be susceptible to localized corrosion in sulfur-chloride-containing environments. It is believed that for localized corrosion of CRAs to occur, sulfur must be in direct contact with the metal. In addition to elemental sulfur and chlorides, the effects of several other variables on localized corrosion were also investigated. The susceptibility to localized corrosion of these CRAs increases with increases in temperature, oxygen, chloride, and sulfur, and with a decrease in the pH of the test solution.
The results of this research correlate well with the observed performance of these two CRA materials in a water disposal well. A model for the localized corrosion of CRAs in a sulfur-chloride-containing solution is described in this paper.