Mixtures of chlorine, hydrogen chloride and small amounts of water, well within the limits found in commercial chlorine, can cause unacceptable corrosion of nickel alloys, including Hastelloy C-276*, and severe corrosion of carbon steel. In the presence of larger amounts of water, it is possible for a series of exothermic chemical reactions to take place that will result in a steel-chlorine fire. Three case histories are presented illustrating the dangers in combining these chemicals and metals.

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