Abstract
Potentiodynamic polarization and linear polarization measurements have been performed on coated and bare pipe steel surfaces in three soils of resistivity ranging from 2,000 to 300,000 ohm- cm. Correction for IR drop effects was employed. The results of these laboratory tests indicate that electrochemical techniques can more clearly identify differences in corrosion resistance than can pipe-to-soil potential measurements and soil resistivity surveys alone. Galvanostatic tests indicated correspondence with Faraday's law when compared with weight loss measurements. A number of different methods for determination of corrosion rates of these materials in soil are compared in this paper. In 14 week tests, a method first described by Oldham and Mansfeld (based upon slight departures from linearity of the polarization curve at low overpotentials) was found, by comparison to weight loss measurements, to be a quantitative method of corrosion rate measurement for pipe steel in soil environments. Preliminary tests showed that A.C. impedance techniques may offer promise for determination of underground corrosion rates also.