A mechanistic model is developed to predict the general corrosion rate at the top of a gas pipeline. This model covers the three main processes involved in the top-of-the-line corrosion (TLC) phenomena: the dropwise condensation, the behavior of the chemistry in the condensed water, and the corrosion at the steel surface. The dropwise condensation process is modeled based on the heat and mass-transfer theory and is used to predict the condensation rate. The breakdown of species concentrations in the droplet is established through the main thermodynamic and chemical equilibrium. The general corrosion rate is predicted using the kinetics of the electrochemical reactions at the steel surface and by taking into account the mass-transfer and chemical reactions occurring inside the droplet. Finally, the accuracy of the predictions of the model is evaluated by comparison with experimental data.
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1 November 2007
Research Article|
November 01 2007
A Mechanistic Model of Top-of-the-Line Corrosion Available to Purchase
Z. Zhang;
Z. Zhang
‡
*Ohio University, Institute for Corrosion and Multiphase Technology, 342 West State St., Athens, OH 45701.
‡Corresponding author. E-mail: [email protected].
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D. Hinkson;
D. Hinkson
*Ohio University, Institute for Corrosion and Multiphase Technology, 342 West State St., Athens, OH 45701.
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M. Singer;
M. Singer
*Ohio University, Institute for Corrosion and Multiphase Technology, 342 West State St., Athens, OH 45701.
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H. Wang;
H. Wang
*Ohio University, Institute for Corrosion and Multiphase Technology, 342 West State St., Athens, OH 45701.
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S. Nes̆ić
S. Nes̆ić
*Ohio University, Institute for Corrosion and Multiphase Technology, 342 West State St., Athens, OH 45701.
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‡Corresponding author. E-mail: [email protected].
Online ISSN: 1938-159X
Print ISSN: 0010-9312
NACE International
2007
CORROSION (2007) 63 (11): 1051–1062.
Citation
Z. Zhang, D. Hinkson, M. Singer, H. Wang, S. Nes̆ić; A Mechanistic Model of Top-of-the-Line Corrosion. CORROSION 1 November 2007; 63 (11): 1051–1062. https://doi.org/10.5006/1.3278321
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