Thin, electrochemically grown oxide films on polycrystalline metals have semiconducting properties that may be investigated by photoelectrochemical techniques; Laser spot scanning can be used to generate photocurrent images or maps that identify the local character of the films, with a resolution of about 1 micron. It has been found that the properties of the films may be different on individual grains of the metal, often having epitaxial ordering relationships with the substrate.

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